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Magnetic properties of the ferrimagnetic cobaltite CaBaCo4O7

2011/04/20 by Zhe Qu, Langsheng Ling, Lei Zhang +2 · 17 citations
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Cobaltite #Condensed matter physics #Ferrimagnetism #Magnetic and transport properties of perovskites and related materials #Magnetic field #Magnetic moment #Magnetization #Materials science #Metallurgy #Moment (physics) #Paramagnetism #Physics #Physics of Superconductivity and Magnetism #cond-mat.str-el

paper · pdf · doi:10.1016/j.ssc.2011.04.013

published in Solid State Communications 151(13), 917-919 (Elsevier BV) · 9 pages, 4 figures. To be published in Solid State Communications

arxiv created 2011/04/20 · openalex publication_date 2011/04/21 · arxiv updated 2015/03/18 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/05

Abstract

The magnetic properties of the ferrimagnetic cobaltite CaBaCo4O7 are systematically investigated. We find that the susceptibility exhibits a downward deviation below ∼ 360 K, suggesting the occurrence of short range magnetic correlations at temperature well above TC. The effective moment is determined to be 4.5 μB/f.u, which is consistent with that expected for the Co2+/Co3+ high spin species. Using a criterion given by Banerjee [Phys. Lett. 12, 16 (1964)], we demonstrate that the paramagnetic to ferrimagnetic transition in CaBaCo4O7 has a first order character.

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