New Results - Wireless Networking

2006/01/01 by Yu Gong, Mingfei Zhou, Martin Kaupp +10 · 2 citations
Chemical Engineering · Chemistry · Computer Science · Engineering · Materials Science · #Catalysis and Oxidation Reactions #Catalytic Processes in Materials Science #Energy Efficient Wireless Sensor Networks #IPv6, Mobility, Handover, Networks, Security #Inorganic Fluorides and Related Compounds #Opportunistic and Delay-Tolerant Networks

paper · doi:10.1002/anie.200902733

openalex publication_date 2006/01/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/06/11

Abstract

A state of eight: Iridium atoms insert into dioxygen to form iridium dioxide molecules in solid noble-gas matrices. Annealing allows formation of the iridium dioxide superoxide complex [(η1-O2)IrO2], which isomerizes under IR irradiation to the iridium dioxide peroxide complex [(η2-O2)IrO2]. These complexes photochemically rearrange to the more stable iridium tetroxide molecule with an iridium oxidation state of +VIII (see scheme; Ir black, O red).

Citations

• Generalized gradient approximation for the exchange-correlation hole of a many-electron system
• Density-functional thermochemistry. III. The role of exact exchange
• Revising the Highest Oxidation States of the 5d Elements: The Case of Iridium(+VII)
• Oxidation State +IV in Group 12 Chemistry. Ab Initio Study of Zinc(IV), Cadmium(IV), and Mercury(IV) Fluorides

Cited by

• Experimental and theoretical identification of the Fe( vii ) oxidation state in FeO 4 −
• Iridium [wikipedia]