1933/12/01 by Hubert M. James, Albert Sprague Coolidge · 4 citations
Mathematics · Physics and Astronomy · #Spectral Theory in Mathematical Physics #Quantum chaos and dynamical systems #Quantum Mechanics and Non-Hermitian Physics
paper · doi:10.1063/1.1749252
openalex publication_date 1933/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/26
The method used by Hylleraas in treating the He atom has been extended to the H2 molecule. The method consists of setting up a wave function as a series in the five variables required, electronic separation being introduced explicitly as one of the variables. The coefficients are then determined so as to produce the lowest energy. The energy found is within 0.03 v.e. of the most probable experimental value, while the form and location of the potential energy curve for various internuclear distances agree with those deduced from spectra to within similar limits. The value of the function is computed for several configurations of the electrons, and compared with other approximations. Application of the method to other problems is discussed. A method is given for the numerical solution of secular equations of high degree.