2013/05/31 by P. Foury-Leylekian, S. Petit, I. Mirebeau +10 · 1 citation
Chemistry · Materials Science · Physics and Astronomy · #Atomic physics #Chemistry #Crystallography #Deuterium #Inorganic Fluorides and Related Compounds #Magnetism in coordination complexes #Materials science #Neutron scattering #Optics #Organic and Molecular Conductors Research #Physics #Scattering #cond-mat.str-el
paper · pdf · doi:10.1103/physrevb.88.024105
published as Physical Review B 88, 024105 (2013)
openalex publication_date 2013/07/10 · arxiv created 2013/07/31 · arxiv updated 2013/08/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/06
We present a detailed low-temperature investigation of the statics and dynamics of the anions and methyl groups in the organic conductors (TMTSF)2PF6 and (TMTSF)2AsF6 (TMTSF: tetramethyl-tetraselenafulvalene). The 4 K neutron-scattering structure refinement of the fully deuterated (TMTSF)2PF6-D12 salt allows locating precisely the methyl groups at 4 K. This structure is compared to the one of the fully hydrogenated (TMTSF)2PF6-H12 salt previously determined at the same temperature. Surprisingly, it is found that deuteration corresponds to the application of a negative pressure of 5\ifmmode×\else\texttimes\fi102 MPa to the H12 salt. Accurate measurements of the Bragg intensity show anomalous thermal variations at low temperature both in the deuterated PF6 and AsF6 salts. Two different thermal behaviors have been distinguished. Small Bragg-angle measurements reflect the presence of low-frequency modes at characteristic energies \ensuremathθE = 8.3 K and \ensuremathθE = 6.7 K for the PF6-D12 and AsF6-D12 salts, respectively. These modes correspond to the low-temperature methyl group motion. Large Bragg-angle measurements evidence an unexpected structural change around 55 K, which probably corresponds to the linkage of the anions to the methyl groups via the formation of F…D-CD2 bonds observed in the 4 K structural refinement. Finally we show that the thermal expansion coefficient of (TMTSF)2PF6 is dominated by the librational motion of the PF6 units. We quantitatively analyze the low-temperature variation of the lattice expansion via the contribution of Einstein oscillators, which allows us to determine for the first time the characteristic frequency of the PF6 librations: \ensuremathθE \ensuremath≈ 50 K and \ensuremathθE = 76 K for the PF6-D12 and PF6-H12 salts, respectively.