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Structure formation of surfactant membranes under shear flow

2013/04/13 by Hayato Shiba, Hiroshi Noguchi, Gerhard Gompper
Chemistry · Engineering · Physics and Astronomy · #Advanced Polymer Synthesis and Characterization #Fluid Dynamics Simulations and Interactions #Surfactants and Colloidal Systems #cond-mat.soft

paper · pdf · doi:10.1063/1.4811239

published as J. Chem. Phys. 139, 014702 (2013) · 12 pages, 13 figures

arxiv created 2013/04/13 · openalex publication_date 2013/07/01 · arxiv updated 2013/07/02 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Shear-flow-induced structure formation in surfactant-water mixtures is investigated numerically using a meshless-membrane model in combination with a particle-based hydrodynamics simulation approach for the solvent. At low shear rates, uni-lamellar vesicles and planar lamellae structures are formed at small and large membrane volume fractions, respectively. At high shear rates, lamellar states exhibit an undulation instability, leading to rolled or cylindrical membrane shapes oriented in the flow direction. The spatial symmetry and structure factor of this rolled state agree with those of intermediate states during lamellar-to-onion transition measured by time-resolved scatting experiments. Structural evolution in time exhibits a moderate dependence on the initial condition.

Citations