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Exact theory of dense amorphous hard spheres in high dimension I. The free energy

2012/08/31 by Jorge Kurchan, Giorgio Parisi, Francesco Zamponi · 1 citation
Engineering · Materials Science · Physics and Astronomy · #Material Dynamics and Properties #Phase Equilibria and Thermodynamics #Theoretical and Computational Physics #cond-mat.dis-nn #cond-mat.stat-mech

paper · pdf · doi:10.1088/1742-5468/2012/10/p10012

published as J. Stat. Mech. (2012) P10012 · 14 pages

arxiv created 2012/10/17 · openalex publication_date 2012/10/17 · arxiv updated 2012/10/18 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/30

Abstract

We consider the theory of the glass transition and jamming of hard spheres in the large space dimension limit. Previous investigations were based on the assumption that the probability distribution within a 'cage' is Gaussian, which is not fully consistent with numerical results. Here we perform a replica calculation without making any assumption on the cage shape. We show that thermodynamic functions turn out to be exact within the Gaussian ansatz—provided one allows for arbitrary replica symmetry breaking—and indeed agree well with numerical results. The actual structure function (the so-called non-ergodic parameter) is not Gaussian, an apparent paradox which we discuss. In this paper we focus on the free energy, future papers will present the results for the structure functions and a detailed comparison with numerical results.

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