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A new magnesium aluminium zirconium oxide, Mg5+x Al2.4−x Zr1.7+0.25x O12 with -0.4≲x≲0.4

1983/12/01 by P. Tassot, G. Konig, G. König +2
Materials Science · Engineering · #Advanced ceramic materials synthesis #Microwave Dielectric Ceramics Synthesis #Magnesium Oxide Properties and Applications

paper · doi:10.1107/s0021889883011279

Abstract

The title compound has been synthesized by sintering oxide mixtures between 1975 and 2175 K. It decomposes at or below ca 1875 K. Quenched to room temperature, the phase is trigonal with a o = 3.2496(1), c 0 = 25.221(1) Å, V = 230.65(2) Å 3 , Z = 1, D m = 3.95(1) g cm −3 , refraction indices ∊ D 293 K = 1.805(5), ω D 293 K = 1.855 (5) and birefringence Δ ′ = 0.05. The JCPDS File No. for magnesium aluminium zirconium oxide is 34-1495.

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