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Synthesis of Shape-Tailored WO3 Micro-/Nanocrystals and the Photocatalytic Activity of WO3/TiO2 Composites

2016/03/31 by István Székely, Gâbor Kovács, Lucian Baia +2 · 1 citation
Energy · Materials Science · #Advanced Photocatalysis Techniques #Transition Metal Oxide Nanomaterials #TiO2 Photocatalysis and Solar Cells

paper · pdf · doi:10.3390/ma9040258

openalex publication_date 2016/03/31 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/30

Abstract

A traditional semiconductor (WO₃) was synthesized from different precursors via hydrothermal crystallization targeting the achievement of three different crystal shapes (nanoplates, nanorods and nanostars). The obtained WO₃ microcrystals were analyzed by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflectance spectroscopy (DRS). These methods contributed to the detailed analysis of the crystal morphology and structural features. The synthesized bare WO₃ photocatalysts were totally inactive, while the P25/WO₃ composites were efficient under UV light radiation. Furthermore, the maximum achieved activity was even higher than the bare P25's photocatalytic performance. A correlation was established between the shape of the WO₃ crystallites and the observed photocatalytic activity registered during the degradation of different substrates by using P25/WO₃ composites.

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