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Field enhancement at metallic interfaces due to quantum confinement

2010/12/03 by Z. Fatih Öztürk, Sanshui Xiao, Min Yan +3 · 2 citations
Chemistry · Physics and Astronomy · #Advanced Physical and Chemical Molecular Interactions #Quantum and electron transport phenomena #Surface and Thin Film Phenomena #cond-mat.mes-hall #physics.optics

paper · pdf · doi:10.1117/1.3574159

published as J. Nanophoton. 5, 051602 (2011)

arxiv created 2010/12/03 · openalex publication_date 2011/01/01 · arxiv updated 2011/04/29 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

We point out an apparently overlooked consequence of the boundary conditions obeyed by the electric displacement vector at air-metal interfaces: the continuity of the normal component combined with the quantum mechanical penetration of the electron gas in the air implies the existence of a surface on which the dielectric function vanishes. This, in turn, leads to an enhancement of the normal component of the total electric field. We study this effect for a planar metal surface, with the inhomogeneous electron density accounted for by a Jellium model. We also illustrate the effect for equilateral triangular nanoislands via numerical solutions of the appropriate Maxwell equations, and show that the field enhancement is several orders of magnitude larger than what the conventional theory predicts.

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