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An overview of corrosion and its control by the surfactants: a mini-review

2025/04/03 by Smitha Shree Subramaniyam, Srilatha Rao, Padmalatha Rao +4 · 5 citations
Engineering · Materials Science · #Biochemical engineering #Chemical engineering #Concrete Corrosion and Durability #Corrosion #Corrosion Behavior and Inhibition #Engineering #Environmental science #Hydrogen embrittlement and corrosion behaviors in metals #Materials science #Metallurgy #Process engineering

paper · doi:10.1080/00084433.2025.2484036

published in Canadian Metallurgical Quarterly 64(4), 2182-2212 (Taylor & Francis)

crossref issued 2025/04/03 · crossref published 2025/04/03 · crossref published-online 2025/04/03 · openalex publication_date 2025/04/03 · crossref created 2025/04/04 · crossref deposited 2025/09/22 · crossref published-print 2025/10/02 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04 · crossref indexed 2026/08/04

Abstract

In recent years, studies of the effectiveness of various surfactant inhibitors in inhibiting corrosion have been published. In acid media, surfactants have generally demonstrated inhibitory efficiency (IE%) ranging from roughly 60% to over 98%. The literature on the cationic, anionic, zwitter ionic, neutral, and Gemini surfactants used to prevent steel corrosion in a range of acidic environments is compiled in this review. Also, the relationship between the amphiphilic nature of surfactants and a lower corrosion rate when using various surfactant classes. The surfactant structures, corrosion rates (CR), free energy of adsorption (ΔG°ads), and acid medium-dependent inhibition efficiencies (IE%) are highlighted. By indicating the connection between surfactants’ molecular structure and adsorption mechanisms, the study presents the most reliable quantitative evaluation of surfactants’ effectiveness as corrosion inhibitors in a range of environmental media. The fact that the majority of inhibitors followed Langmuir adsorption isotherm suggested a systematic adsorption mechanism.

Citations