2003/01/16 by Xile Hu, Yongjun Tang, P. Gantzel +1 · 2 citations
Chemistry · #Carbene #Catalysis #Catalytic Cross-Coupling Reactions #Chemistry #Crystallography #Ligand (biochemistry) #Metal #N-Heterocyclic Carbenes in Organic and Inorganic Chemistry #Organic chemistry #Organoboron and organosilicon chemistry #Polymer chemistry #Receptor #Stereochemistry #Transition metal carbene complex
paper · doi:10.1021/om020935j
openalex publication_date 2003/01/16 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/16
A novel N-heterocyclic tridentate polycarbene ligand has been synthesized and stabilized as its corresponding silver complex. An electronic structure investigation reveals significant π-bonding interactions within the Ag−carbene unit of the [(TIME Me ) 2 Ag 3 ] 3+ cation.