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Thermodynamic consistency of energy and virial routes: An exact proof within the linearized Debye–Hückel theory

2009/10/31 by Andrés Santos, Riccardo Fantoni, Achille Giacometti
Chemistry · Earth and Planetary Sciences · Engineering · Physics and Astronomy · #Electrostatics and Colloid Interactions #High-pressure geophysics and materials #Thermodynamic and Structural Properties of Metals and Alloys #cond-mat.soft #cond-mat.stat-mech #physics.chem-ph

paper · pdf · doi:10.1063/1.3265991

published as J. Chem. Phys. 131, 181105 (2009) · 4 pages, 1 figure; v2: minor changes

openalex publication_date 2009/11/13 · arxiv created 2009/11/14 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

The linearized Debye-Hückel theory for liquid state is shown to provide thermodynamically consistent virial and energy routes for any potential and for any dimensionality. The importance of this result for bounded potentials is discussed.

Citations