2008/05/29 by M.R. Warren, Mya Warren, Jörg Rottler +1
Materials Science · Physics and Astronomy · #Ageing #Composite material #Dynamics (music) #Glass properties and applications #Glass transition #Material Dynamics and Properties #Materials science #Physics #Polymer #Polymer crystallization and properties #Quantum mechanics #Rejuvenation #Relaxation (psychology) #Superposition principle #Thermodynamics #cond-mat.soft
paper · pdf · doi:10.1088/0953-8984/20/24/244131
published as J. Phys: Condens. Matter, 20, 244131 (2008) · 13 pages, 8 figures
openalex publication_date 2008/05/29 · arxiv created 2008/08/13 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/06
Molecular dynamics simulations are used to investigate the connection between thermal history and physical ageing in polymer glasses, in particular the effects of a temperature square step. Measurements of two-time correlation functions show that a negative temperature step causes 'rejuvenation' of the sample: the entire spectrum of relaxation times appears identical to that of a younger specimen that did not experience a temperature step. A positive temperature step, however, leads to significant changes in the relaxation times. At short times, the dynamics are accelerated (rejuvenation), whereas at long times the dynamics are slowed (over-ageing). All findings are in excellent qualitative agreement with recent experiments. The two regimes can be explained by the competing contributions of dynamical heterogeneities and faster ageing dynamics at higher temperatures. As a result of this competition, the transition between rejuvenation and over-ageing depends on the length of the square step, with shorter steps causing more rejuvenation and longer steps causing more over-ageing. Although the spectrum of relaxation times is greatly modified by a temperature step, the van Hove functions, which measure the distribution of particle displacements, exhibit complete superposition at times when the mean squared displacements are equal.