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Vibrational spectroscopy ofH2<mml:none/><mml:none/>+: Precise evaluation of the Zeeman effect

2008/06/10 by Jean-Philippe Karr, Jean‐Philippe Karr, V. I. Korobov +2 · 1 citation
Chemistry · Physics and Astronomy · #Atomic and Molecular Physics #Spectroscopy and Laser Applications #Spectroscopy and Quantum Chemical Studies #quant-ph

paper · pdf · doi:10.1103/physreva.77.062507

published as Physical Review A: Atomic, Molecular and Optical Physics 77, 6 (2008) 062507

openalex publication_date 2008/06/10 · arxiv created 2008/06/12 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

We present an accurate computation of the g factors of the hyperfine states of the hydrogen molecular ion H2+. The results are in good agreement with previous experiments, and can be tested further by rf spectroscopy. Their implication for high-precision two-photon vibrational spectroscopy of H2+ is also discussed. It is found that the most intense hyperfine components of two-photon lines benefit from a very small Zeeman splitting.

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