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Frustration effects in magnetic molecules

2005/01/17 by R. Schmidt, Johannes Richter, J. Richter +2 · 1 citation
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Magnetism in coordination complexes #Physics of Superconductivity and Magnetism #cond-mat.str-el

paper · pdf · doi:10.1016/j.jmmm.2005.01.009

published as Journal of Magnetism and Magnetic Materials 295 (2005) 164-167 · 4 pages, 7 figures

arxiv created 2005/01/17 · openalex publication_date 2005/02/01 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

By means of exact diagonalization we study the ground-state and the low-temperature physics of the Heisenberg antiferromagnet on the cuboctahedron and the icosidodecahedron. Both are frustrated magnetic polytopes and correspond to the arrangement of magnetic atoms in the magnetic molecules Cu12La8 and Mo72Fe30. The interplay of strong quantum fluctuations and frustration influences the ground state spin correlations drastically and leads to an interesting magnetization process at low temperatures. Furthermore the frustration yields low-lying non-magnetic excitations resulting in an extra low-temperature peak in the specific heat.

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