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Fluoride effect on plasma electrolytic oxidation coating formed on Mg-Al alloy in alkaline electrolytes

2019/12/12 by Lishi Wang, Tao Feng, Shanwen Yu +3 · 1 citation
Chemistry · Engineering · Materials Science · #Alloy #Aluminium #Aluminum Alloys Composites Properties #Amorphous solid #Chemical engineering #Chemistry #Coating #Composite material #Electrode #Electrolyte #Fluoride #Hydrogen Storage and Materials #Inorganic chemistry #Layer (electronics) #Magnesium #Magnesium Alloys: Properties and Applications #Magnesium fluoride #Materials science #Metallurgy #Nanocrystalline material #Nanotechnology #Oxide #Plasma electrolytic oxidation #Substrate (aquarium) #Titanium

paper · doi:10.1088/2053-1591/ab60a7

openalex publication_date 2019/12/12 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/25

Abstract

Abstract Plasma electrolytic oxidation (PEO) is an effective protection technique developed for light alloys, such as aluminum, magnesium and titanium alloys. PEO electrolytes often contain fluorides, yet their functionality is not well understood during the oxide layer formation and growth. In the present work, we tracked the fluoride evolvement contained in PEO ceramic protective layer formed on AZ91 magnesium alloys. It is found that a fluoride rich layer with 1–2 μ m thickness is often formed at the coating/substrate interface and nanocrystalline MgO islands with size of 20–60 nm are found to be embedded in amorphous coating substrate.

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