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ChemInform Abstract: Phenoxo and Diphenoxo Complexes of Titanium(III) and Vanadium(III): Synthesis and X‐Ray Structure.

1989/12/05 by Marinella Mazzanti, C. Floriani, Angiola Chiesi‐Villa +1 · 1 citation
Chemistry · #Vanadium and Halogenation Chemistry #Metal-Catalyzed Oxygenation Mechanisms #Oxidative Organic Chemistry Reactions

paper · doi:10.1002/chin.198949239

openalex publication_date 1989/12/05 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Abstract The 1:1 molar reaction of the V(III) complex (I) or its Ti(III) analogue with sodium 2,6‐dialkylphenolates such as (II) leads to the monomeric five‐coordinate complexes (IIIa) (space group P2 1 /n, Z=4) and (IIIb) (yield 62%; P2 1 /c, Z=4).

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