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Molecular hydrodynamic theory of supercooled liquids and colloidal suspensions under shear

2002/11/18 by Kunimasa Miyazaki, David R. Reichman · 5 citations
Materials Science · Physics and Astronomy · #Material Dynamics and Properties #Spectroscopy and Quantum Chemical Studies #Theoretical and Computational Physics #cond-mat.stat-mech

paper · pdf · doi:10.1103/physreve.66.050501

published as Physical Review E, Vol. 66 (2002) 050501R · 5 pages, 1 figure

openalex publication_date 2002/11/18 · arxiv created 2003/04/08 · arxiv updated 2009/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04

Abstract

We extend the conventional mode-coupling theory of supercooled liquids to systems under stationary shear flow. Starting from generalized fluctuating hydrodynamics, a nonlinear equation for the intermediate scattering function is constructed. We evaluate the solution numerically for a model of a two-dimensional colloidal suspension and find that the structural relaxation time decreases as \stackrel\ifmmode \else \.\fi\ensuremathγ^\ensuremath-\ensuremathν with an exponent \ensuremathν<~1, where \stackrel\ifmmode \else \.\fi\ensuremathγ is the shear rate. The results are in qualitative agreement with recent molecular dynamics simulations. We discuss the physical implications of the results.

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