2003/04/01 by C. P. Adams, J. W. Lynn, V. N. Smolyaninova +9 · 3 citations
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Magnetic and transport properties of perovskites and related materials #Rare-earth and actinide compounds #cond-mat.str-el #cond-mat.supr-con
paper · pdf · doi:10.1103/physrevb.70.134414
13 pages, 16 figures, submitted to Phys. Rev. B
arxiv created 2003/04/01 · openalex publication_date 2004/10/20 · arxiv updated 2009/11/30 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28
Neutron scattering has been used to study the nature of the ferromagnetic transition in single crystals of La0.7Ca0.3MnO3 and La0.8Ca0.2MnO3, and polycrystalline samples of La0.67Ca0.33MnO3 and La5∕8Ca3∕8MnO3 where the naturally occurring 16O can be replaced with the 18O isotope. Small angle neutron scattering on the x=0.3 single crystal reveals a discontinuous change in the scattering at the Curie temperature for wave vectors below \ensuremath≈0.065\phantom\rule0.3em0ex\mathrm\AA^\ensuremath-1. Strong relaxation effects are observed for this domain scattering, for the magnetic order parameter, and for the quasielastic scattering, demonstrating that the transition is not continuous in nature, in good agreement with the temperature dependence of the central component of the magnetic fluctuation spectrum, the polaron correlations, and the spin stiffness reported previously. This behavior contrasts with the continuous behavior observed for the x=0.2 crystal, which is well away from optimal doping. There is a large oxygen isotope effect observed for the TC in the polycrystalline samples, and the Curie temperature is decreased by 7\phantom\rule0.3em0exK by substituting 50% 18O in the x=0.33 sample. For the optimally doped x=3∕8 sample we observed TC(16O)=266.5\phantom\rule0.3em0exK and TC(18O)=261.5\phantom\rule0.3em0exK at 90% 18O substitution. Although TC is decreased by 5\phantom\rule0.3em0exK for the x=3∕8 sample the temperature dependence of the spin-wave stiffness is found to be identical for the two samples. These results indicate that TC is not solely determined by the magnetic subsystem, but instead the ferromagnetic phase is truncated by the formation of polarons which cause an abrupt transition to the paramagnetic, insulating state. The application of uniaxial stress in the x=0.3 single crystal sharply enhances the polaron scattering at room temperature. Measurements of the phonon density-of-states show only modest differences above and below TC and between the two different isotopic samples.