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Crystal field − AS z 2 does not produce one-phonon transitions with Δ S z = ±2 (Comment on “Spin relaxation in Mn 12 -acetate” by M. N. Leuenberger and D. Loss)

2000/05/22 by E. M. Chudnovsky, E. M Chudnovsky, D. A. Garanin +1 · 1 citation
Chemistry · Materials Science · Physics and Astronomy · #Advanced Physical and Chemical Molecular Interactions #Magnetism in coordination complexes #Organic and Molecular Conductors Research #cond-mat.mtrl-sci #cond-mat.stat-mech

paper · pdf · doi:10.1209/epl/i2000-00412-2

published as Europhys. Lett., 52 (2), p. 245 (2000) · 2 pages, no figures, submitted to EPL

arxiv created 2000/05/22 · openalex publication_date 2000/10/15 · arxiv updated 2009/11/30 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

Recently Leuenbeger and Loss suggested a theory of phonon-assisted relaxation in a molecular nanomagnet Mn-12 that "contrary to previous results is in reasonably good agreement ... with all experimental parameter values known so far". The purpose of this Comment is to show that the model of Leuenberger and Loss and its comparison with experiment are premised upon their incorrect use of the linear formula for the strain tensor. The spin-phonon coupling introduced by Leuenberger and Loss disappears if the nonlinear term in the strain tensor is taken into account.

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