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Exact results for kinetics of catalytic reactions

1995/08/25 by L. Frachebourg, P. L. Krapivsky · 1 citation
Mathematics · Physics and Astronomy · #Complex Network Analysis Techniques #Stochastic processes and statistical mechanics #Theoretical and Computational Physics #cond-mat

paper · pdf · doi:10.1103/physreve.53.r3009

4 pages, RevTeX, no figures

arxiv created 1995/08/25 · openalex publication_date 1996/04/01 · arxiv updated 2009/11/30 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

The kinetics of an irreversible catalytic reaction on a substrate of arbitrary dimension is examined. In the limit of infinitesimal reaction rate (reaction-controlled limit), we solve the dimer-dimer surface reaction model (or voter model) exactly in arbitrary dimension D. The density of reactive interfaces is found to exhibit a power-law decay for D<2 and a slow logarithmic decay in two dimensions. We discuss the relevance of these results for the monomer-monomer surface reaction model.

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