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Tetragonal-to-Orthorhombic Structural Phase Transition at 90 K in the SuperconductorFe1.01Se

2009/05/07 by T. M. McQueen, Tyrel M. McQueen, A. J. Williams +12 · 1 citation
Materials Science · Physics and Astronomy · #Iron-based superconductors research #Rare-earth and actinide compounds #cond-mat.str-el #cond-mat.supr-con

paper · pdf · doi:10.1103/physrevlett.103.057002

published as Phys. Rev. Lett. 103, 057002 (2009) · 5 pages, 5 figures

arxiv created 2009/05/07 · openalex publication_date 2009/07/30 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

In this Letter we show that superconducting Fe(1.01)Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that nonsuperconducting Fe(1.03)Se does not. High resolution electron microscopy at low temperatures further reveals an unexpected additional modulation of the crystal structure of the superconducting phase that involves displacements of the Fe atoms, and that the nonsuperconducting composition shows a different, complex nanometer-scale structural modulation. Finally, we show that magnetism is not the driving force for the phase transition in the superconducting phase.

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