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Structural complexity in monodisperse systems of isotropic particles

2008/07/05 by Michael Engel, Hans-Rainer Trebin
Materials Science · Physics and Astronomy · #Amorphous solid #Dispersity #Isotropy #Material Dynamics and Properties #Particle (ecology) #Particle system #Phase (matter) #Phase diagram #Pickering emulsions and particle stabilization #Quasicrystal Structures and Properties #Structural complexity #cond-mat.mtrl-sci #cond-mat.soft

paper · pdf · doi:10.1524/zkri.2008.1040

published as Zeitschrift fur Kristallographie 223, 721-725 (2008) · 10 pages, 5 figures, Proceedings of the 10th International Conference on Quasicrystals

arxiv created 2008/07/05 · openalex publication_date 2008/12/01 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

Abstract It has recently been shown that identical, isotropic particles can form complex crystals and quasicrystals. In order to understand the relation between the particle interaction and the structure, which it stabilizes, the phase behavior of a class of two-scale potentials is studied. In two dimensions, the phase diagram features many phases previously observed in experiment and simulation. The three-dimensional system includes the sigma phase with 30 particles per unit cell, not grown in simulations before, and an amorphous state, which we found impossible to crystallize in molecular dynamics. We suggest that the appearance of structural complexity in monodisperse systems is related to competing nearest neighbor distances and discuss implications of our result for the self-assembly of macromolecules.

Citations