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Palladium-CatalyzedCross-Coupling of Iodocarboraneswith B2pin2

2026/07/27 by Xuan-Hao Cao, Xuanhao Cao, Wen-Jin Zou +2
Chemistry · Medicine · #Bond #Boron Compounds in Chemistry #Neonatal Health and Biochemistry #Organoboron and organosilicon chemistry #Surface modification #Work (physics)

paper · doi:10.1021/acs.inorgchem.6c02922

openalex publication_date 2026/07/27 · openalex created_date 2026/07/28 · openalex updated_date 2026/08/05

Abstract

Abstract This work discloses a palladium-catalyzed borylation of the B–I bond of carboranes with B2pin2. A series of 9-Bpin-o-carborane and 9-Bpin-m-carborane derivatives have been synthesized with moderate to good yields. This work has important references for functionalization of the B–I bond of carboranes.