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Helix or coil? Fate of a melting heteropolymer

2008/07/07 by G. Oshanin, S. Redner · 40 citations
Chemistry · Materials Science · Physics and Astronomy · #Advanced Physical and Chemical Molecular Interactions #Block Copolymer Self-Assembly #Helix (gastropod) #Interval (graph theory) #Material Dynamics and Properties #Melting temperature #Monomer #Polymer #Probability distribution #cond-mat.soft #cond-mat.stat-mech

paper · pdf · doi:10.1209/0295-5075/85/10008

published in Europhysics Letters (EPL) 85(1), 10008 (Institute of Physics) · 4 pages, 5 figures

arxiv created 2008/07/07 · openalex publication_date 2009/01/01 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

We study the probability that a partially melted heteropolymer at the melting temperature will either melt completely or return to a helix state. This system is equivalent to the splitting probability for a diffusing particle on a finite interval that moves according to the Sinai model. When the initial fraction of melted polymer is g , the melting probability fluctuates between different realizations of monomer arrangements on the chain. For a fixed value of g , the melting probability distribution changes from unimodal to a bimodal as the strength of the disorder is increased.

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