Architectural Spiroligomers Designed for Binuclear Metal Complex Templating

2013/05/13 by Shivaiah Vaddypally, Chongsong Xu, Senzhi Zhao +3 · 1 citation
Chemistry · Chemical Engineering · #N-Heterocyclic Carbenes in Organic and Inorganic Chemistry #Synthesis and characterization of novel inorganic/organometallic compounds #Carbon dioxide utilization in catalysis

paper · doi:10.1021/ic4003498

openalex publication_date 2013/05/13 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/23

Abstract

The first structurally, spectroscopically, and electronically characterized metal-spiroligomer complexes are reported. The binuclear [M2L2](4+) ions (M = Mn, Zn) are macrocyclic "squares" and are characterized by X-ray diffraction, (1)H and (13)C NMR, electronic absorption, emission, and mass spectroscopies. The manganese complex contains two spin-independent Mn(II) ions and is additionally characterized using EPR and CD spectroscopies and CV.

Citations

• A Spiroligomer α-Helix Mimic That Binds HDM2, Penetrates Human Cells and Stabilizes HDM2 in Cell Culture
• Shape-Programmable Macromolecules
• Living alkene polymerization: New methods for the precision synthesis of polyolefins
• Single-crystal structure validation with the programPLATON
• Synthesis of Hexa- and Pentasubstituted Diketopiperazines from Sterically Hindered Amino Acids

Cited by

• Spiroligomer [wikipedia]

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