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Engineering molecular aggregate spectra

2008/09/16 by A. V. Malyshev, V. A. Malyshev
Engineering · Physics and Astronomy · #Spectroscopy and Quantum Chemical Studies #Strong Light-Matter Interactions #Surface Chemistry and Catalysis #cond-mat.dis-nn #cond-mat.mtrl-sci

paper · pdf · doi:10.1002/pssc.200879867

published as phys. stat. sol. (c) 6, 224 (2009) · 4 two-column pages, Proceedings of the 8th International Conference on Excitonic Processes in Condensed Matter, June 22-27, Kyoto, Japan

arxiv created 2008/09/16 · openalex publication_date 2008/10/16 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/04

Abstract

Abstract We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole‐dipole interactions of monomers with their images can result in strong re‐structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Citations