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Intrinsic properties of stoichiometric LaFePO

2008/05/14 by Tyrel M. McQueen, T. M. McQueen, Michelle D. Regulacio +10
Business, Management and Accounting · Materials Science · Physics and Astronomy · #Corporate Taxation and Avoidance #Iron-based superconductors research #Rare-earth and actinide compounds #cond-mat.str-el #cond-mat.supr-con

paper · pdf · doi:10.1103/physrevb.78.024521

published as Phys. Rev. B 78, 024521 (2008) · Submitted to PRB Rapid Comm

arxiv created 2008/05/14 · openalex publication_date 2008/07/29 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

DC and ac magnetization, resistivity, specific-heat, and neutron-diffraction data reveal that stoichiometric LaFePO is metallic and non-superconducting above T=0.35 K, with \ensuremathγ=12.5\fracmJmol K2. Neutron-diffraction data at room temperature and T=10 K are well described by the stoichiometric, tetragonal ZrCuSiAs structure, and show no signs of structural distortions or long-range magnetic ordering to an estimated detectability limit of 0.07\ensuremathμB/Fe. We propose a model based on the shape of the iron-pnictide tetrahedron that explains the differences between LaFePO and LaFeAsO, the parent compound of the recently discovered high-Tc oxyarsenides, which, in contrast, shows both structural and spin-density wave transitions.

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