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Ultratransparent glass ceramics: The structure factor and the quenching of the Rayleigh scattering

2007/08/06 by M. Mattarelli, M. Montagna, P. Verrocchio · 2 citations
Materials Science · Physics and Astronomy · #Glass properties and applications #Luminescence Properties of Advanced Materials #Photonic Crystals and Applications #cond-mat.mtrl-sci

paper · pdf · doi:10.1063/1.2768642

published as Appl. Phys. Lett. 91, 061911 (2007) · 9 pages, 2 fig

openalex publication_date 2007/08/06 · arxiv created 2008/06/06 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Glass ceramics with nanocrystals present a transparency higher than that expected from the theory of Rayleigh scattering. This ultratransparency is attributed to the spatial correlation of the nanoparticles. The structure factor is calculated for a simple model system, the random sequential addition of equal spheres, at different volume filling factor. The spatial correlation given by the constraint that particles cannot superimpose produces a diffraction peak with a low S(q) in its low-q tail, which is relevant for light scattering. The physical mechanism producing high transparency in glass ceramics is demonstrated to be the low density fluctuation in the number of scatterers.

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