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Theoretical Evidence for a Reentrant Phase Diagram in Ortho-Para Mixtures of SolidH2at High Pressure

2005/03/02 by Balázs Hetényi, Balazs Hetenyi, Sandro Scandolo +1
Earth and Planetary Sciences · Physics and Astronomy · #Atomic and Subatomic Physics Research #High-pressure geophysics and materials #Quantum, superfluid, helium dynamics #cond-mat.mtrl-sci #cond-mat.stat-mech

paper · pdf · doi:10.1103/physrevlett.94.125503

published as Phys. Rev. Lett. 94 125503 (2005) · 4 pages, 5 figures, to appear in Physical Review Letters

arxiv created 2005/03/02 · openalex publication_date 2005/03/30 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

We develop a multiorder parameter mean-field formalism for systems of coupled quantum rotors. The scheme is developed to account for systems where ortho-para distinction is valid. We apply our formalism to solid H2 and D2. We find an anomalous reentrant orientational phase transition for both systems at thermal equilibrium. The correlation functions of the order parameter indicate short-range order at low temperatures. As the temperature is increased the correlation increases along the phase boundary. We also find that even extremely small odd-J concentrations (1%) can trigger short-range orientational ordering.

Citations