Relativistic corrections ofmα6order to the rovibrational spectrum ofH2<mml:none/><mml:none/>+andHD+molecular ions

2007/11/28 by V. I. Korobov · 4 citations
Decision Sciences · Earth and Planetary Sciences · Physics and Astronomy · #Atmospheric Ozone and Climate #Atomic and Molecular Physics #Scientific Measurement and Uncertainty Evaluation #physics.atom-ph

paper · pdf · doi:10.1103/physreva.77.022509

published as Phys. Rev. A 77, 022509 (2008) · 4 pages, 1 figure

arxiv created 2007/11/28 · openalex publication_date 2008/02/28 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

The major goal of high-precision studies of rovibrational states in the hydrogen molecular ions is to provide an alternative way for improving the electron-to-proton mass ratio, or the atomic mass of electron. By now the complete set of relativistic and radiative corrections have been obtained for a wide range of rovibrational states of H₂⁺ and HD⁺ up to order R_\ensuremath∞\ensuremathα⁴. In this work we complete calculations of various contributions to the R_\ensuremath∞\ensuremathα⁴ order by computing the relativistic corrections to the binding energy of electron.

Citations

• Theory of Light Hydrogenlike Atoms
• Relativistic corrections of ordermα6to the two-centre problem

Cited by

• Vibrational spectroscopy ofH2<mml:none/><mml:none/>+: Hyperfine structure of two-photon transitions
• Observation of a rotational transition of trapped and sympathetically cooled molecular ions
• The Physics behind Chemistry and the Periodic Table
• Manipulation of Individual Hyperfine States in Cold Trapped Molecular Ions and Application toHD+Frequency Metrology