Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

2004/01/01 by Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada · 2 citations
Chemistry · #Organometallic Complex Synthesis and Catalysis #Catalytic Cross-Coupling Reactions #Asymmetric Hydrogenation and Catalysis

paper · doi:10.1039/b308741g

openalex publication_date 2004/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/30

Abstract

The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(ii) complexes, trans-Pd(C(6)F(5))I(PR(3))(2)(PR(3)= PEt(3), PMe(2)Ph, PMePh(2)) in the presence of Ag(2)O afforded trans-Pd(C(6)F(5))(2,4,6-C(6)F(3)H(2))(PR(3))(2) which are stabilized by fluorine atoms in the ortho positions.

Citations

• Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme

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