2006/04/26 by Kelvin L. Billingsley, Kevin W. Anderson, Stephen L. Buchwald · 2 citations
Chemistry · Biochemistry, Genetics and Molecular Biology · #Catalytic Cross-Coupling Reactions #Catalytic C–H Functionalization Methods #Chemical Synthesis and Analysis
paper · pdf · doi:10.1002/anie.200600493
openalex publication_date 2006/04/26 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01
Unprecedented activity: Catalysts derived from Pd and bulky dialkylphosphinobiaryl ligands are shown to be highly stable and active in Suzuki–Miyaura reactions of heteroaryl halides and heteroaryl boronic acids/esters (e.g., 3- or 4-pyridine, indole, and N-protected pyrrole derivatives). Furthermore, this catalyst system is not inhibited by the presence of highly basic aminopyridines or aminopyrimidines.