Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

2011/01/01 by Laura J. Sewell, Adrian B. Chaplin, Andrew S. Weller · 1 citation
Chemistry · Materials Science · Medicine · #Boron Compounds in Chemistry #Hydrogen Storage and Materials #Organoboron and organosilicon chemistry

paper · doi:10.1039/c1dt10819k

openalex publication_date 2011/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22

Abstract

The catalytic hydroboration of tert-butylethene using H(3)B·NMe(3) gives RH(2)B·NMe(3). With H(3)B·NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu).

Cited by

• Amine-boranes [wikipedia]

Related

• Uncovering the role of boronic acids and boroxines in the catalytic hydroboration of alkenes
• Dehydrocoupling Reactions of Borane−Secondary and −Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines
• Cobalt-Catalyzed Hydroboration and Borylation of Alkenes and Alkynes
• Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane
• The transition metal-catalysed hydroboration reaction