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Structural properties and optical response of Na clusters in Ne, Ar, and Kr matrices

2007/06/14 by F. Fehrer, Phuong Mai Dinh, P. M. Dinh +3 · 1 citation
Physics and Astronomy · #Advanced Chemical Physics Studies #Cold Atom Physics and Bose-Einstein Condensates #Quantum, superfluid, helium dynamics #cond-mat.other

paper · pdf · doi:10.1103/physrevb.75.235418

published as Phys. Rev. B 75, 235418 (2007) · 9 pages, 3 figures, 1 table accepted in Phys. Rev. B

arxiv created 2007/06/14 · openalex publication_date 2007/06/14 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We discuss the structural properties and optical response of a small Na cluster inside rare-gas (RG) matrices of Ne, Ar, or Kr atoms. The mixed systems are described with a hierarchical model, treating the cluster at a quantum-mechanical level and the matrix atoms classically in terms of their positions and polarizations. We pay special attention to the differences caused by the different matrix types. These differences can be explained by the interplay of core repulsion and dipole attraction in the interaction between the cluster electrons and the RG atoms.

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