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Julia–Colonna asymmetric epoxidation of furyl styryl ketone as a route to intermediates to naturally-occurring styryl lactones

1999/01/01 by Weiping Chen, Stanley M. Roberts · 3 citations
Biochemistry, Genetics and Molecular Biology · Chemistry · #Marine Sponges and Natural Products #Synthetic Organic Chemistry Methods #Traditional and Medicinal Uses of Annonaceae

paper · doi:10.1039/a808436j

openalex publication_date 1999/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

The enone 1 was oxidized stereoselectively using urea-hydrogen peroxide with polyeucine as the catalyst to give the epoxide 2 which was used to make (+)-goniotriol 7, (+)-goniofufurone 8, (+)-8-acetylgonitriol 9 and gonio-pypyrone 10.

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