Comparison of Anionic and Lewis Acid Stabilized N‐Heterocyclic Oxoboranes: Their Facile Synthesis from a Borinic Acid

2011/02/21 by Yan Wang, Hongfan Hu, Jianying Zhang +1 · 1 citation
Chemistry · #Coordination Chemistry and Organometallics #Organoboron and organosilicon chemistry #Synthesis and characterization of novel inorganic/organometallic compounds

paper · doi:10.1002/ange.201007417

openalex publication_date 2011/02/21 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/29

Abstract

BO im Doppelpack: Metallfreie anionische Oxoborane und Lewis-Säure-stabilisierte Oxoborane mit formaler B-O-Doppelbindung lassen sich leicht aus einer N-heterocyclischen Borinsäure in Gegenwart von N-heterocyclischen Carbenen (NHCs) bzw. Lewis-Säuren erhalten (siehe Schema).

Citations

• Synthesis and Characterization of a Coordinated Oxoborane: Lewis Acid Stabilization of a Boron−Oxygen Double Bond
• π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
• Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum

Cited by

• Oxoborane [wikipedia]

Related

• Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines
• Synthesis and Comparative Characterization of 9‐Boraanthracene, 5‐Boranaphthacene, and 6‐Borapentacene Stabilized by the H2IMes Carbene
• From bis(borylene)-substituted xanthenes as reactive intermediates to diboraoxirane complexes
• α-Borylcarbene precursors: design, generation, and synthetic opportunities
• Stable Yet Strongly Lewis‐Acidic Anions Enabling Cooperative Catalysis with Cationic Transition‐Metal Complexes