Sulfidkontraktion via alkylative Kupplung: Eine methode zur darstellung von β‐dicarbonylderivaten. Über synthetische methoden, 1. Mitteilung

1971/01/01 by Martin M. Roth, Paul Dubs, Erwin Götschi +1 · 3 citations
Chemistry · #Advanced Synthetic Organic Chemistry #Asymmetric Synthesis and Catalysis #Chemical synthesis and alkaloids

paper · doi:10.1002/hlca.19710540229

openalex publication_date 1971/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/26

Abstract

Abstract The experiments described in reaction schemes 1–12 indicate that sulfide contraction via alkylative coupling (see scheme p. 729) is a potentially general method for the synthesis of secondary vinylogous amides and enolizable β‐dicarbonyl compounds.

Citations

• HEXAMETHYLPHOSPHOROUS TRIAMIDE
• Recent advances in the chemistry of natural products
• A New Type of Corrin Synthesis

Cited by

• One-Pot Eschenmoser Episulfide Contractions in DMSO: Applications to the Synthesis of Fuligocandins A and B and a Number of Vinylogous Amides
• A new synthetic method of 1β-methylcarbapenems utilizing the eschenmoser sulfide contraction
• Eschenmoser sulfide contraction [wikipedia]