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Remarkably Stable Chalcogen(II) Dications

2009/10/05 by Caleb D. Martin, Christine M. Le, Paul J. Ragogna · 1 citation
Chemistry · Medicine · #Organometallic Complex Synthesis and Catalysis #Metal complexes synthesis and properties #Synthesis and characterization of novel inorganic/organometallic compounds

paper · doi:10.1021/ja9073968

openalex publication_date 2009/10/05 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/17

Abstract

Air-stable, chalcogen-centered dications have been synthesized and comprehensively characterized. These represent the first diiminopyridine (DIMPY) complexes of the chalcogens as well as the single nonmetallic (sulfur) complex of this ubiquitous ligand. Their stability under ambient conditions is a distinct contrast to other highly charged main-group cations.

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