2004/10/15 by Alexandrù T. Balaban · 1 citation
Chemistry · Biochemistry, Genetics and Molecular Biology · Medicine · #Carbohydrate Chemistry and Synthesis #Chemical Synthesis and Analysis #Synthesis of Organic Compounds
paper · doi:10.1002/047084289x.rn00509
openalex publication_date 2004/10/15 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/29
[38222-83-2] C14H23N (MW 205.34) InChI = 1S/C14H23N/c1-10-8-11(13(2,3)4)15-12(9-10)14(5,6)7/h8-9H,1-7H3 InChIKey = HVHZEKKZMFRULH-UHFFFAOYSA-N (sterically hindered non-nucleophilic Brønsted base that may be protonated by Brønsted acids but does not react with Lewis acids) Alternate Name: 2,6-bis(1,1-dimethylethyl)-4-methylpyridine, DTBMP. Physical Data: mp 34 °C; bp 223 °C/760 Torr, 150 °C/95 Torr; nD20 1.4763; Fp 84 °C; enthalpy of vaporization: 45 kJ/mol; vapor pressure 0.087 Torr at 25 °C; pKa 4.41 (50% EtOH). Solubility: sparingly soluble in H2O at pH > 7, slightly soluble at pH 4, and soluble at pH 1; soluble in EtOH, AcOH, Et2O, Me2CO. Form Supplied in: white solid at temperatures lower than 30 °C. Purification: chromatography on activated alumina, recrystallization from cold pentane, sublimation, or distillation under reduced pressure. Handling, Storage, and Precautions: may be stored indefinitely; irritant, potentially toxic, handle with care. Use in a fume hood. salts trifluoromethanesulfonate, mp 203 °C; hexachloroplatinate mp 213–214 °C (dec.).