Bis(allyl)calcium

2009/06/27 by Phillip Jochmann, T.S. Dols, Thomas P. Spaniol +3 · 3 citations
Chemistry · #Catalytic Cross-Coupling Reactions #Coordination Chemistry and Organometallics #Organometallic Complex Synthesis and Catalysis

paper · pdf · doi:10.1002/anie.200901743

openalex publication_date 2009/06/27 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

Bis(allyl)calcium is surprisingly stable and has good solubility in THF. The compound crystallizes as a triglyme adduct (see picture; C gray, O red). Selective CC coupling to give 1,5-hexadiene is observed upon reaction with iodine.

Cited by

• The Allylcalcium Monocation: A Bridging Allyl Ligand with a Non‐Bent Coordination Geometry
• Dimethylcalcium
• Group 2 organometallic chemistry [wikipedia]

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