One-Pot Synthesis ofN-Substituted Diaza[12]annulenes

2006/08/16 by Isao Yamaguchi, Yoshiaki Gobara, Moriyuki Sato · 4 citations
Chemistry · #Synthesis and Properties of Aromatic Compounds #Fullerene Chemistry and Applications #Organic Chemistry Cycloaddition Reactions

paper · doi:10.1021/ol061585q

openalex publication_date 2006/08/16 · openalex created_date 2016/06/24 · openalex updated_date 2026/06/26

Abstract

N-Substituted diaza[12]annulenes are obtained by one -pot reaction of N-(2,4-dinitrophenyl)pyridinium chloride with amines in moderate to high yields. The 1H NMR spectrum reveals that diamagnetic ring current is generated in the diaza[12]annulene ring. The N-substituted diaza[12]annulenes are electrochemically active in solution.

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