The modified Julia olefination: alkene synthesis via the condensation of metallated heteroarylalkylsulfones with carbonyl compounds

2002/11/04 by Paul R. Blakemore · 2 citations
Chemistry · #Synthetic Organic Chemistry Methods #Chemical Synthesis and Reactions #Phosphorus compounds and reactions

paper · doi:10.1039/b208078h

openalex publication_date 2002/11/04 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Covering: until May 2002.

Citations

• The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects
• A direct synthesis of olefins by reaction of carbonyl compounds with lithio derivatives of 2-[alkyl- or (2′-alkenyl)- or benzyl-sulfonyl]-benzothiazoles.
• New developments in the Peterson olefination reaction
• The Utility of Phosphonate Carbanions in Olefin Synthesis
• Use of Samarium Diiodide as an Alternative to Sodium/Mercury Amalgam in the Julia-Lythgoe Olefination

Cited by

• Total Synthesis of Iejimalide B. An Application of the Shiina Macrolactonization
• Julia olefination [wikipedia]