2008/03/14 by Jiro Tsuji, Ian J. S. Fairlamb · 1 citation
Chemistry · #Catalytic Cross-Coupling Reactions #Coordination Chemistry and Organometallics #Catalytic C–H Functionalization Methods
paper · doi:10.1002/047084289x.rt400.pub2
openalex publication_date 2008/03/14 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/29
[52522-40-4] C52H43Cl3O3Pd2 (MW 1035.14) InChI = 1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+;;; InChIKey = LNAMMBFJMYMQTO-FNEBRGMMSA-N (air-stable Pd0 complex used directly as homogeneous Pd0 catalyst with or without ligand) Physical Data: mp 122–124 °C (dec),1 131–135 °C.2 Solubility: insol H2O; sol chloroform, benzene. Form Supplied in: deep purple needle-like crystals; commercially available. Preparative Methods: the reaction of Na2[Pd2Cl6] (from Palladium(II) Chloride and NaCl) and dibenzylideneacetone (dba) gives Bis(dibenzylideneacetone)palladium(0), [Pd(dba)2], which is formulated more correctly as [Pd2(dba)3]dba.1, 3 Recrystallization from chloroform displaces the uncoordinating dba with chloroform to give the title reagent as deep purple needles.1