Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure

2011/08/23 by Kerry Gilmore, Igor V. Alabugin · 3 citations
Chemistry · #Catalytic Alkyne Reactions #Chemistry #Click Chemistry and Applications #Closure (psychology) #Combinatorial chemistry #Computational chemistry #Cyclopropane Reaction Mechanisms #Organic chemistry #Ring (chemistry) #Stereochemistry

paper · doi:10.1021/cr200164y

openalex publication_date 2011/08/23 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/30

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTCyclizations of Alkynes: Revisiting Baldwin's Rules for Ring ClosureKerry Gilmore and Igor V. Alabugin*View Author Information Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida, 32306-4390E-mail: [email protected]Cite this: Chem. Rev. 2011, 111, 11, 6513–6556Publication Date (Web):August 23, 2011Publication History Received11 May 2011Published online23 August 2011Published inissue 9 November 2011https://pubs.acs.org/doi/10.1021/cr200164yhttps://doi.org/10.1021/cr200164yreview-articleACS PublicationsCopyright © 2011 American Chemical SocietyRequest reuse permissionsArticle Views18819Altmetric-Citations447LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Anions,Cyclization,Hydrocarbons,Selectivity,Substitution reactions Get e-Alerts

Citations

• A Strain-Promoted [3 + 2] Azide−Alkyne Cycloaddition for Covalent Modification of Biomolecules in Living Systems
• On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I
• Assessment of Nucleophilicity and Electrophilicity of Radicals, and of Polar and Enthalpy Effects on Radical Addition Reactions1
• Rules for Anionic and Radical Ring Closure of Alkynes
• Gold(I)‐Catalyzed 5‐endo‐dig Carbocyclization of Acetylenic Dicarbonyl Compounds
• Stereoelectronic Effects

Cited by

• The Baldwin rules: revised and extended
• Silver‐Catalyzed Three‐Component 1,1‐Aminoacylation of Homopropargylamines: α‐Additions for Both Terminal Alkynes and Isocyanides
• Baldwin's rules [wikipedia]

Related

• Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes
• Cyclizations of enolates onto aromatic rings via the photo-SRN1 reaction. Preparative and mechanistic aspects
• The Baldwin rules: revised and extended
• Transition Metal Chemistry of Cyclopropenes and Cyclopropanes
• Biosynthesis and Metabolism of Cyclopropane Rings in Natural Compounds