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First detection of triply-deuterated methanol

2003/11/03 by B. Parise, A. Castets, E. Herbst +4 · 5 citations
Physics and Astronomy · #Astronomy and Astrophysical Research #Astrophysics and Star Formation Studies #Stellar, planetary, and galactic studies #astro-ph

paper · pdf · doi:10.1051/0004-6361:20034490

published as Astronomy and Astrophysics 416 (2004) 159-163 · Accepted by A&A

arxiv created 2003/11/03 · openalex publication_date 2004/02/23 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/01

Abstract

We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main isotopomer CH3OH. The derived fractionation ratio [ CD3OH] /[ CH3OH] averaged on a 10'' beam is 1.4%. Together with previous CH2DOH and CHD2OH observations, the present CD3OH observations are consistent with a formation of methanol on grain surfaces, if the atomic D/H ratio is 0.1 to 0.3 in the accreting gas. Such a high atomic ratio can be reached in the framework of gas-phase chemical models including all deuterated isotopomers of H.

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