2009/09/16 by Shunsuke Furukawa, Junji Kobayashi, Takayuki Kawashima · 2 citations
Chemistry · #Organoboron and organosilicon chemistry #Synthesis and characterization of novel inorganic/organometallic compounds #Synthesis and Properties of Aromatic Compounds
paper · doi:10.1021/ja906566r
openalex publication_date 2009/09/16 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/09
An intramolecular sila-Friedel-Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availability as a versatile synthetic method. The synthesis of trisilasumanene, a silicon analogue of sumanene, was achieved using the present reaction.