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The preparation and characterization by Raman spectroscopy of Pl 4 + AsF 6 – containing the tetraiodophosphonium cation

1990/01/01 by Inis Tornieporth-Getting, Thomas M. Klapötke · 1 citation
Chemistry · Materials Science · #Inorganic Fluorides and Related Compounds #Inorganic Chemistry and Materials #Luminescence Properties of Advanced Materials

paper · doi:10.1039/c39900000132

openalex publication_date 1990/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/08

Abstract

The thermodynamically unstable PI4+AsF6- containing the first and only example of a tetrahedral PI4+4 cation, formally a derivative of the unknown PI5, was prepared by the reaction of PI3 and I3+AsF6– at low temperatures and characterized by Raman spectroscopy.

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