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Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants

2010/10/14 by D. Bradley G. Williams, Michelle Lawton · 5 citations
Environmental Science · Chemistry · #Chemistry and Chemical Engineering #Various Chemistry Research Topics #History and advancements in chemistry

paper · doi:10.1021/jo101589h

openalex publication_date 2010/10/14 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31

Abstract

Various commonly used organic solvents were dried with several different drying agents. A glovebox-bound coulometric Karl Fischer apparatus with a two-compartment measuring cell was used to determine the efficiency of the drying process. Recommendations are made relating to optimum drying agents/conditions that can be used to rapidly and reliably generate solvents with low residual water content by means of commonly available materials found in most synthesis laboratories. The practical method provides for safer handling and drying of solvents than methods calling for the use of reactive metals, metal hydrides, or solvent distillation.

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