3(or 5)-Formyl-2-furan(or pyrrole)carboxylates and 3(4 or 5)-Formyl-2-furan(or pyrrole)-carboxamides via Alkoxycarbonylation or Carbamoylation of Stannylated Formyl Heterocycles

1993/01/01 by B. Jousseaume, Hee-An Kwon, Jean‐Baptiste Verlhac +2 · 2 citations
Medicine · Chemistry · Pharmacology, Toxicology and Pharmaceutics · #Synthesis of Organic Compounds #Synthesis and Biological Evaluation #Fluorine in Organic Chemistry

paper · doi:10.1055/s-1993-22368

openalex publication_date 1993/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04

Abstract

(opens in new window) Buy Article (opens in new window) Permissions and Reprints (opens in new window) All articles of this category (opens in new window) The palladium-catalyzed cross-coupling reaction between 5-tributylstannyl-2(3 or 4)-furancarbaldehydes or N-methyl-5-tributylstannyl-2-pyrrolecarbaldehyde and chloroformates or carbamoyl chlorides produces the corresponding formyl heterocyclic esters or amides in good yields, without protection of the reactive formyl group.

Cited by

• The S tille Reaction
• Stille reaction [wikipedia]